Gọi n KMnO4 = a 

       n KClO3 = b ( mol ) 

--> 158a + 122,5 b = 43,3 

PTHH :

\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\uparrow\)

0,9b                       1,35b

\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)

0,9a                                             0,45a 

\(\%Mn=\dfrac{55a}{43,3-32\left(0,45a+1,35b\right)}=24,103\%\)

\(\rightarrow a=0,15\)

\(b=0,16\)

\(m_{KMnO_4}=0,15.158=23,7\left(g\right)\)

\(m_{KClO_3}=0,16.122,5=19,6\left(g\right)\)

Z gồm CO2 và O2 dư

$C + O_2 \xrightarrow{t^o} CO_2$

$n_{CO_2} =n_{O_2\ pư} =  n_C = \dfrac{1,128}{12} = 0,094(mol)$

Gọi $n_{O_2} = 2a \to n_{không\ khí} = 3a(mol)$

Trong Y : 

$n_{O_2} = 2a + 3a.20\% = 2,6a(mol)$
$n_{N_2} = 3a.80\% = 2,4a(mol)$

Trong Z : 

$n_{CO_2} = 0,094(mol)$
$n_{N_2} = 2,4a(mol)$
$n_{O_2\ dư} = n_{O_2} - n_{O_2\ pư} = 2,6a - 0,094(mol)$

m CO2 =0,094.44 = 4,136(gam)

=> m Z = 4,136 : 27,5% = 15,04(gam)

SUy ra : 

4,136 + 2,4a.28 + (2,6a - 0,094).32 = 15,04

=> a = 0,0925

=> n O2 = 0,0925.2 = 0,185(mol)

m X = 43,5 : 46,4% = 93,75(gam)

Bảo toàn khối lượng : m = 93,75 + 0,185.32 = 99,67(gam)

Chọn đáp án D

PT: \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\) (1)

\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\) (2)

\(C+O_2\underrightarrow{t^o}CO_2\) (3)

Ta có: \(n_{KCl}=\dfrac{1,49}{74,5}=0,02\left(mol\right)\)

\(n_C=\dfrac{0,24}{12}=0,02\left(mol\right)\)

\(m_Y=\dfrac{1,49}{17,028\%}=8,75\left(g\right)\), Y gồm: KCl, KMnO_4 (dư), K₂MnO₄, MnO₂.

Theo PT (3): \(n_{CO_2}=n_{O_2\left(pư\right)}=n_C=0,02\left(mol\right)\)

\(\Rightarrow n_{O_2\left(dư\right)}=\dfrac{0,02}{40\%}-0,02=0,03\left(mol\right)\)

⇒ Σn_O2 = 0,02 + 0,03 = 0,05 (mol)

Theo PT (1): \(n_{O_2\left(1\right)}=\dfrac{3}{2}n_{KCl}=0,03\left(mol\right)\)

\(\Rightarrow n_{O_2\left(2\right)}=0,05-n_{O_2\left(1\right)}=0,02\left(mol\right)\)

Theo PT (2): \(n_{K_2MnO_4}=n_{MnO_2}=n_{O_2\left(2\right)}=0,02\left(mol\right)\)

\(n_{KMnO_4\left(pư\right)}=2n_{O_2}=0,04\left(mol\right)\)

Mà: m_KCl + m_{KMnO4 (dư)} + m_K2MnO4 + m_MnO2 = 8,75

⇒ m_{KMnO4 (dư)} = 1,58 (g) \(\Rightarrow n_{KMnO_4\left(dư\right)}=\dfrac{1,58}{158}=0,01\left(mol\right)\)

\(\Rightarrow H\%=\dfrac{0,04}{0,04+0,01}.100\%=80\%\)

\(a,n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ PTHH:2K+2H_2O\rightarrow2KOH+H_2\uparrow\\ Theo.pt:n_K=2n_{H_2}=2.0,1=0,2\left(mol\right)\\ m_K=0,2.39=7,8\left(g\right)\\ m_{K_2O}=17,2-7,8=9,4\left(g\right)\\ b,n_{CuO\left(bđ\right)}=\dfrac{12}{80}=0,15\left(mol\right)\\ PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ LTL:0,15>0,1\Rightarrow Cu.dư\)

Gọi n_{CuO (pư)} = a (mol)

=> n_Cu = a (mol)

m_{chất rắn sau pư} = 80(0,15 - a) + 64a = 10,8

=> a = 0,075 (mol)

=> n_{H2 (pư)} = 0,075 (mol)

\(H=\dfrac{0,075}{0,1}=75\%\)

Chọn đáp án C